Синтез и исследование родийсодержащих катализаторов гидролиза боргидрида натрия тема диссертации и автореферата по ВАК РФ 02.00.15, кандидат химических наук Нецкина, Ольга Владимировна

• Нецкина, Ольга Владимировна
• кандидат химических наук
• 2011

Список литературы диссертационного исследования кандидат химических наук Нецкина, Ольга Владимировна, 2011 год

1. Susai Т., Kawakami A., Hamada A., Miyake Y. and Azegami Y. Development of a 1 kW РЕМ fuel cell power source // Fuel Cells Bulletin. - 2001. - V. 3. - № 29. - P. 7-11.

2. Рабинович B.A., Хавин З.Я. Краткий химический справочник. JI.: Химия, 1977. - 376 с.

3. Kong V.C.Y., Foulkes F.R., Kirk D.W., Hinatsu J.T. Development of hydrogen storage for fuel cellgenerators. I: Hydrogen generation using hydrolysishydrides // International Journal of Hydrogen Energy. 1999. - V. 24. - № 7. - P. 665-675.

4. Kojima Y., Suzuki K., Fukumoto K., Kawai Y., Kimbara M., Nakanishi H., Matsumoto S. Development of 10 kW-scale hydrogen generator using chemical hydride // Journal of Power Sources. 2004. - V. 125. - № 1. - P. 22-26.

5. Gervasio D., Tasic S., Zenhausern F. Room temperature micro-hydrogen-generator // Journal of Power Sources.-2005.-V. 149.-№26.-P. 15-21.

6. Galli S., De Francesco M., Monteleone G., Oronzio R., Pozio A. Development of a compact hydrogen generator from sodium borohydride // International Journal of Hydrogen Energy. 2010.- V. 35. № 14. - P. 7344-7349.

7. Hsueh C.-L., Liu C.-H., Chen B.-H., Lee M.-S., Chen C.-Y., Lu Y.-W., Tsau F., Ku J.-R. A novel design of solid-state NaBH4 composite as a hydrogen source for 2 W PEMFC applications // Journal of Power Sources. -2011. -V. 196. -№ 7. P. 3530-3538.

8. Holbrook K.A., Twist P.J. Hydrolysis of the borohydride ion catalysed by metal-boron alloys // Journal of the Chemical Society A: Inorganic, Physical, Theoretical. 1971. - P. 890 - 894.

9. Вальсюнене Я.И., Норгайлайте А.Ю. Электрохимическое исследование каталитического разложения ВН4 на Rh // Труды Академии наук Литовской ССР. Серия Б. 1975. - Т. 6. -№91.-С. 11-15.

10. Demirci U.B., Miele P. Sodium tetrahydroborate as energy/hydrogen carrier, its history // Comptes Rendus Chimie. 2009. - V. 12. - № 9. - P. 943-950.

11. Demirci U.B., Akdim O., Miele P. Ten-year efforts and a no-go recommendation for sodium borohydride for on-board automotive hydrogen storage // International Journal of Hydrogen Energy.- 2009. V. 34. - № 6. - P. 2638-2645.

12. Jiang H.-L., Singh S.K., Yan J.-M., Zhang X.-B., Xu Q. Liquid-Phase Chemical Hydrogen Storage: Catalytic Hydrogen Generation under Ambient Conditions // ChemSusChem. 2010. - V. 3. -№ 5. - P. 541-549.

13. Demirci U. В., Akdim O., Andrieux J., Hannauer J., Chamoun R., Miele P. Sodium Borohydride Hydrolysis as Hydrogen Generator: Issues, State of the Art and Applicability Upstream from a Fuel Cell // Fuel Cells/ 2010. - V. 10. -№ 3. p. 335-350.

14. Andrieux J., Demirci U.B., Hannauer J., Gervais C., Goutaudier C., Miele P. Spontaneous hydrolysis of sodium borohydride in harsh conditions // International Journal of Hydrogen Energy. 2011.-V. 36.-№ 1.-P. 224-233.t

15. Marrero-Alfonso E.Y., Gray J.R., Davis T.A., Matthews M.A. Minimizing water utilization in hydrolysis of sodium borohydride: The role of sodium metaborate hydrates // International Journal of Hydrogen Energy. 2007. V. 32. - № 18. - P. 4723-4730.

16. Liu B.H., Li Z.P., Suda S. Influences of alkali in borates on recovery of sodium borohydride // Journal of Alloys and Compounds. 2009. - V. 474. - № 1-2. - P. L6-L9.

17. Gunn S.R., Green R.G. The heat of solution of sodium borohydride and the entropy of borohydride ion // Journal of the American Chemical Society. — 1955. V. 77. - № 23. - P. 61976198.

18. Damjanovic L., Bennici S., Auroux A. A direct measurement of the heat evolved during the sodium and potassium borohydride catalytic hydrolysis // Journal of Power Sources. 2010. - V. -195.-№ 10.-P. 3284-3292.

19. Zhang J., Fisher T.S., Gore J.P., Hazra D., Ramachandran P.V. Heat of reaction measurements of sodium borohydride alcoholysis and hydrolysis // International Journal of Hydrogen Energy. -2006. V. 31. - № 15. - P. 2292-2298.

20. Davis R.E., Swein C.C. General acid catalysis of the hydrolysis of sodium borohydride // Journal of the American Chemical Society. 1960. - V. 82. - № 22. - P. 5949-5950.

21. Davis R.E., Bromels E., Kibby C.L. Boron hydrides. III. Hydrolysis of sodium borohydride in aque-ous solution. // Journal of the American Chemical Society. 1962. - V. 84. - № 6. - P. 885892.

22. Мочалов K.H., Шифрин X.B., Богоносцев A.C. Кинетика гидролиза борогидрида калия // Кинетика и катализ. 1964. - Т. 5. - №1. - С. 174-177.

23. Kreevoy M.M., Hutchins J.E.C, H2BH3 as intermediate in tetrahydridoborate hydrolysis // Journal of the American Chemical Society. 1972. - V. 94. - № 18. - P. 6371-6376.

24. Willen R. Possible mechanisms of the reaction between tetrahydroborate and hydrogen ion: A permutational analysis. // Journal of the Chemical Society, Dalton Transactions. 1979. - V. 1. - P. 33-40.

25. Schreiner P.R., Schaefer H.F., von Ragué Schleyer P. The structure and stability of BH5. Does correlation make it a stable molecule? Qualitative changes at high levels of theory // Journal of Chemical Physics. 1994.-V. 101.-P. 7625.

26. Custelcean R. Ab initio comparative study of BH4CN and BH5 // Journal of Molecular Structuré: THEOCHEM. 2000. -V. 505. -№ 1-3. - P. 95-101.

27. Davis R.E. Boron hydrides. 4 Concerning the geometry of the activated complex in hydrolysis of borohydride ion by trimethylammonium ion. // Journal of the American Chemical Society. -1962. V. 84.-№ 6. - P. 892-894.

28. Levine L.A., Kreevoy M.M. Solvent isotope effects on tetrahydridoborate hydrolysis. Journal of the American Chemical Society. 1972. - V. 94. - № 10 - P. 3346-3349.

29. Duke B.J., Gulbert J.R., Read I.A. Preparation and purification of diborane // Journal of the Chemical Society A: Inorganic, Physical, Theoretical. 1964. - P. 540-542.

30. Kaufman C.M., Sen B., Hydrogen generation by hydrolysis of sodium tetrahydroborate: effects of acids and transition metals and their salts // Journal of the Chemical Society, Dalton Transactions. 1985. - P. 307 - 313.

31. Akdim O., Demirci U.B., Miele P. Acetic acid, a relatively green single-use catalyst for hydrogen generation from sodium borohydride // International Journal of Hydrogen Energy. 2009. -V. 34.-№ 17.-P. 7231-7238.

32. Javed U., Subramanian V. Hydrogen Generation Using a Borohydride-Based Semi-continuous Milli-scale Reactor: Effects of Physicochemical Parameters on Hydrogen Yield // Energy & Fuels. -2009. -V. 23. -№ l.-P. 408-413.

33. Мочалов К.Н., Хаин B.C., Гильманшин Г.Г. Кинетическое изучение промежуточных стадий гидролиза ВН4"-иона // Кинетика и катализ. 1965. - Т. 6. - С. 541-543.

34. Мочалов К.Н., Хаин B.C., Гильманшин Г.Г. Обобщенная схема гидролиза борогидрид-иона и диборана // Доклады академии наук СССР. 1965. - Т. 162. - № 3. - С. 613-616.

35. Хаин B.C., Волков А.А. О стабильности водных растворов тетрагидроборатов натрия и калия. // Журнал прикладная химия. 1980. - Т. 53. - С. 2404-2407.

36. Minkina V.G., Shabunya S.I., Kalinin V.I., Martynenko Y.V., Smirnova A.L. Long-term stability of sodium borohydrides for hydrogen generation // International Journal of Hydrogen Energy. 2008. - V. 33. - № 20. - P. 5629-5635.

37. Liu B.H., Li Z.P., Suda S. Thermal properties of alkaline sodium borohydride solutions // Thermochimica Acta. -2008. V. 471.-№ 1-2.-P. 103-105.

38. Kim H.J., Shin K.-J., Kim H.-J., Han M.K., Kim H., Shul Y.-G., Jung К. T. Hydrogen generation from aqueous acid-catalyzed hydrolysis of sodium borohydride // International Journal of Hydrogen Energy. 2010. - V. 35. - № 22. - P. 12239-12245.

39. Moon G.Y., Lee S.S., Lee K.Y., Kim S.H., Song K.H. Behavior of hydrogen evolution of aqueous sodium borohydride solutions // Journal of Industrial and Engineering Chemistry. 2008. -V. 14.-№ l.-P. 94-99.

40. Brown M.C., Brown C.A. New, highly active metal catalysts for the hydrolysis of borohydride //Journal of the American Chemical Society. 1962. -V. 84. -№ 8. - P. 1493-1494.

41. Стерлядкина 3.K., Мальцева H.H., Франгулян Г.Д., Полковников Б.Д., Бакулина В.М. О катализаторах, получаемых восстановлением солей металлов VIII группы боргидридом натрия // Известия Академии наук СССР. Серия Химия. 1972. - Т. 21. — С. 1240-1245.

42. Dragieva I., Mehandjiev D., Lefterova E., Stoycheva M., Stoynov Z. Mechanism of borohydride reduction process and properties of obtained nanosized ferromagnetic particles // Journal of Magnetism and Magnetic Materials. 1995. - V. 140-144.- P. 455-456.

43. Lefterova E., Dragieva I., Tchanev V., Mehandjiev D., Mikhov M. Crystallographic phases in nanosized ferromagnetic particles obtained by two different methods // Journal of Magnetism and Magnetic Materials. 1995. - V. 140-144. - P. 457-458.

44. Chen Y. Chemical preparation and characterization of metal-metalloid ultrafine amorphous alloy particles // Catalysis Today. 2001. - V. 44. - P. 3-16.

45. Jackelen A.M.L., Jungbauer M., Glavee G.N. Nanoscale Materials Synthesis. 1. Solvent Effects on Hydridoborate Reduction of Copper Ions // Langmuir. 1999. - V. 15. - № 7. - P. 2322-2326.

46. Варущенко B.M., Полковников Б.Д., Богдановский Г.А., Акимов В.М. Исследование адсорбции водорода на «боридных» катализаторах металлов платиновой группы // Известия АН СССР. Сер. хим. 1972. - Т. 7. - С. 1662-1665.

47. Шалкаускене Ю.А. Каталитическое окисление борогидрида натрия на меди: Дис. . к.х.н.: 02.073 / Ю.А. Шалкаускене. ВГУ им. В. Капсукаса. Вильнюс, 1972. - 134 с.

48. Hohnstedt L.F., Miniatas В.О., Waller М.С. Aqueous Sodium Borohydride Chemistry. The Coinage Metals, Copper, Silver, and Gold // Analytical Chemistry. 1965. - V. 37. - № 9. - P. 1163-1164.

49. Schaeffer G.W., Waller M.C., Hohnstedt L.F. Aqueous Sodium Borohydride Chemistry. Lead, Barium, Mercury, Cadmium, and Zinc // Analytical Chemistry. 1961. -V. 33. -№ 12. - P. 1719— 1722.

50. Garron A., Bennici S., Auroux A. In situ generated catalysts for NaBbLi hydrolysis studied by liquid-phase calorimetry: Influence of the nature of the metal // Applied Catalysis A: General. -2010. -V. 378. -№ 1.- P. 90-95.

51. Прокопчик А.Ю., Вальсюнене Я.И. Каталитическое разложение NaBH4 на Rh // Труды Академии наук Литовской ССР. Серия Б. 1974. - Т. 4. - № 83. - С. 11-19.

52. Прокопчик А.Ю., Вальсюнене Я.И., Норгайлайте А.Ю. Каталитическое разложение ВН4 на Ru // Труды Академии наук Литовской ССР. Серия Б. 1974. Т. 5. - № 84. - С. 17-24.

53. Прокопчик А.Ю., Вальсюнене Я.И., Винкявичюс И.И. Каталитическое разложение ВН4 на Pt // Труды Академии наук Литовской ССР. Серия Б. 1976. - Т. 2. - № 93. - С. 3-11.

54. Прокопчик А.Ю., Вальсюнене Я.И., Кашкялис А.С. Каталитическое разложение ВН4 наiPd // Труды Академии наук Литовской ССР. Серия Б. 1977. - Т. 6. - № 103. - С. 3-9.

55. Krishnan P., Yang T.-H., Lee W.-Y., Kim C.-S. PtRu-LiCo02—an efficient catalyst for hydrogen generation from sodium borohydride solutions // Journal of Power Sources. 2005. - V. 143.1-2. P. 17-23.

56. Demirci U.B., Garin F. Promoted sulphated-zirconia catalysed hydrolysis of sodium tetrahydroborate // Catalysis Communications. 2008. - V. 9. - № 6. - P. 1167-1172.

57. Chen Y., Kim H. Use of a nickel-boride-silica nanocomposite catalyst prepared by in-situ reduction for hydrogen production from hydrolysis of sodium borohydride // Fuel Processing Technology. 2008. - V. 89. - № 10. - P. 966-972.

58. Walter J.C., Zurawski A., Montgomery D., Thornburg, Revankar S. Sodium borohydride hydrolysis kinetics comparison for nickel, cobalt, and M. ruthenium boride catalysts // Journal of Power Sources.-2008.-V. 179.-№ l.-P. 335-339.

59. Demirci U.B., Garin F. Kinetics of Ru-promoted sulphated zirconia catalysed hydrogen generation by hydrolysis of sodium tetrahydroborate // Journal of Molecular Catalysis A: Chemical.- -2008.-V. 279.-№ l.-P. 57-62.

60. Chamoun R., Demirci B., Cornu D., Zaatar Y., Khoury R., Khoury A., Miele P. From soil tolab: Utilization of clays as catalyst supports in hydrogen generation from sodium borohydride fuel //iFuel.-2011.-V. 90.-№5.-P. 1919-1926.

61. Zahmakiran M., Ozkar S. Water dispersible acetate stabilized ruthenium(O) nanoclusters as catalyst for hydrogen generation from the hydrolysis of sodium borohyride // Journal of Molecular Catalysis A: Chemical. 2006. - V. 258. - № 1-2. - P. 95-103.

62. Ozkar S., Zahmakiran M. Hydrogen generation from hydrolysis of sodium borohydride using Ru(0) nanoclusters as catalyst // Journal of Alloys and Compounds. 2005. - V. 404-406. - P. 728731.

63. Fernandes R., Patel N., Miotello A. Hydrogen generation by hydrolysis of alkaline NaBH» 'solutioniwith Cr-promoted; Co-B amorphous catalyst' // Applied Catalysis B: Environmental; 2009. V. 92. - № 1-2. - P. 68-74.

64. Shang Y., Chen- R., Jiang G.Kinetic study of-'NaBKU hydrolysis over carbon-supported ruthenium // International Journal of Hydrogen Energy. 2008. -V. 33 . - № 22. - P. 6719-6726.

65. Liu Z., Guo Bl, Chan S;H:, Tang E.Hi, Hong E. Pt and Ru dispersed on LiCo02 for hydrogen generation from sodium borohydride solutions // Journal of Power Sources. 2008. - V. 176. -№ 1. -P. 306-311. .

66. Rakap M., Ozkar S. Intrazeolite cobalt(O) nanoclusters as low-cost and;reusable catalyst for hydrogen generation from .the hydrolysis , of; sodium' borohydride // Applied- Catalysis B: Environmental. 2009. - V. 91. - № 1-2. - P. 21-29: - r : " .

67. Liu C.-H., Chen B -II., Hsueh C.-L., Ku J.-R., Jeng M.-S., Tsau F. Hydrogen generation-from hydrolysis of sodium borohydride using Ni-Ru:nanocomposite as catalysts ;// International Journal of Hydrogen Energy. 2009.* - V. 34; - Xa 5. - P: 2153-2163;

68. Amendola S.C., Sharp-Goldman S.L:, Janjua M.S., Kelly M.T., Petillo P.J., Binder M: An ultrasafe hydrogen generator: aqueous, alkaline borohydride solutions and Ru catalyst // Journal of Power Sources. 2000. - V. 85 - № 2. — P. 186-189.

69. Pena-Alonso R., Sicurelli A., Callone E., Carturan G., Raj R. A picoscale catalyst for hydrogen generation from NaBH4 for fuel cells // Journal of Power Sources. 2007. - V. 165. - № 1. - P.315.323.

70. Dai H.-B., Liang Y., Ma L.-P., Wang P. New Insights into Catalytic Hydrolysis Kinetics of . Sodium Borohydride from Michaelis-Menten Model // Journal of Chemical Physics. C. 2008.V. 112.-№40.-P. 15886-15892.

71. Demirci U.B., Garin F. Promoted sulphated-zirconia catalysed hydrolysis of sodium tetrahydroborate // Catalysis Communications. 2008. - V. 9. - № 6. - P. 1167-1172.

72. Patel N., Fernandes R., Miotello A. Hydrogen generation by hydrolysis of NaBKU with efficient Co-P-B catalyst: A kinetic study // Journal of Power Sources. 2009. - V. 188. - № 2. - P. 411420.

73. Zhang Q., Wu Y., Sun X., Ortega J. Kinetics of Catalytic Hydrolysis of Stabilized Sodium Borohydride Solutions // Industrial & Engineering Chemistry Research. 2007. - V. 46. - № 4. -P. 1120-1124.

74. Liu B.H., Li' Z.P., Suda S. Nickel- and cobalt-based catalysts for hydrogen generation by hydrolysis of borohydride // Journal of Alloys and Compounds. 2006. — V. 415. - № 1-2. — P. 288-293.

75. Metin O., Ozkar S. Hydrogen Generation from the Hydrolysis of Ammonia-borane and Sodium Borohydride Using Water-soluble Polymer-stabilized Cobalt(O) Nanoclusters Catalyst // Energy & Fuels. 2009. - V. 23. - № 7. - P. 3517-3526.

76. Chen Y., Kim H. Use of a nickel-boride-silica nanocomposite catalyst prepared by in-situ reduction for hydrogen production from hydrolysis of sodium borohydride // Fuel, Processing Technology.-2008.-V. 89.-№ 10.-P. 966-972.

77. Боресков Г.К. Гетерогенный катализ. Москва: Наука, 1986. - 304 с.

78. Ни L., Ceccato R., Raj R. Superefficient thin film multilayer catalyst for generating hydrogen from sodium borohydride // Journal of Power Sources. 2011. - V. 196. - № 2. - P. 741-746.

79. ПанченковГ. M:, Лебедев В. П. Химическая кинетика и катализ. Учебное пособие для вузов. М.: Химия,1985. - 592 с.

80. Hua D., Hanxi Y., Xinping A., Chuansin C. Hydrogen production from catalytic hydrolysis of sodium borohydride solution using nickel boride catalyst // International Journal of Hydrogen Energy.-2003.-V. 28. -№ Ю.-Р. 1095-1100.

81. Прокопчик А.Ю., Вальсюнене ЯМ., Кимтене Д.П. Каталитическое разложение NaBH4 на Ni // Труды Академии наук Литовской ССР. Серия Б. 1970. - Т. 4. -№ 63. - С. 27-34.

82. Прокопчик А.Ю, Вальсюнене Я.И. Каталитическое разложение NaBHt на Со // Труды Академии наук Литовской ССР. Серия Б. 1971.-Т. 1.-№64. — С. 13-19.

83. Крылов О.В. Гетерогенный катализ. Часть 1. Учебное пособие. Новосибирск: Новосибирский государственный университет, 2002. — 222 с.

84. Zhang J.S., Delgass W.N., Fisher T.S., Gore J.P. Kinetics of Ru-catalyzed sodium borohydride hydrolysis // Journal of Power Sources. 2007. - У. 164. - № 2. - P. 772-781.

85. Hung A.-J., Tsai S.-F., Hsu Y.-Y., Ku J.-R., Chen Y.-H., Yu C.-C. Kinetics of sodium borohydride hydrolysis reaction for hydrogen generation // International Journal of Hydrogen Energy. 2008. - V. 33. -№ 21. - P. 6205-6215.

86. Прокопчик А.Ю., Шалкаускене Ю.А. Каталитическое разложение NaBHt на Си // Труды Академии наук Литовской ССР. Серия Б. 1971. - Т. 1. - № 64. - С. 3-11.

87. Kishida S., Teranish S. Kinetics of liquid-phase hydrogenation of acetone over Raney nickel catalyst // Journal of Catalysis. 1968. - V.12. - № 1. - P. 90-96.

88. Andrieux J., Demirci U.B., Miele P. Langmuir-Hinshelwood kinetic model to capture the cobalt nanoparticles-catalyzed hydrolysis of sodium borohydride over a wide temperature range // Catalysis Today.-2011.-V. 170.-№ l.-P. 13-19.

89. Mesmer R.E., Jolly W.L. The Hydrolysis of Aqueous Hydroborate // Inorganic Chemistry. -1962.-V. l.-№3.-P. 608-612.

90. Elder J.P., Hickling A. Anodic behaviour of the borohydride ion // Transactions of the Faraday Society. 1962. -V. 58. - P. 1852-1864.

91. Damjanovic L., Majchrzak M., Bennici S., Auroux A. Determination of the heat evolved during sodium borohydride hydrolysis catalyzed by C03O4 // International Journal of Hydrogen Energy. -2011. -V. 36. -№ 3. P. 1991-1997.

92. Маккей К. Водородные соединения металлов. М.: Мир, 1968. - 244 с.

93. Прокопчик А.Ю., Вальсюнене Я.И. Каталитическая активность Pt в растворе ВН4 // Труды Академии наук Литовской ССР. Серия Б. 1978. - Т. 2. - № 105. - С. 3-98.

94. Guella G., Zanchetta С., Patton В., Miotello A. New Insights on the Mechanism of Palladium-Catalyzed Hydrolysis of Sodium Borohydride from nB NMR Measurements // Journal of Physical Chemistry: В.-2006.-V. 110.-№34.-P. 17024-17033.

95. Guella G., Patton В., Miotello A. Kinetic Features of the Platinum Catalyzed Hydrolysis of Sodium Borohydride from UB NMR Measurements // Journal of Physical Chemistry: C. 2007. -V. 111. - № 50. - P. 18744-18750.

96. Liu C.-H., Chen B.-H., Hsueh C.-L., Ku J.-R., Tsau F., Hwang K.-J. Preparation of magnetic cobalt-based catalyst for hydrogen generation from alkaline NaBHj solution Applied Catalysis B: Environmental. 2009. - V. 91. - № 1-2. - P. 368-379.

97. Rostamikia G., Janik M.J. First principles mechanistic study of borohydride oxidation over the Pt(l 11) surface // Electrochimica Acta. 2010. - V. 55. - № 3. - P. 1175-1183.

98. Справочник химика: Общие сведения, строение вещества, свойства важнейших веществ, лабораторная техника. Под редакцией чл-корр. Б.П. Никольского, Т.1. Л.: Химия, 1966. -1072 с.

99. Michaelides А , Ranea V.A., de Andres P.L., King D.A. General Model for Water Monomer Adsorption on Close-Packed Transition and Noble Metal Surfaces // Physical Review Letters. -2003. V. 90. -№ 21ю - P. 216102-1 - 216102-4.

100. Fajin J.L.C., Cordeiro M.N.D.S., Illas F., Gomes J.R.B. Descriptors controlling the catalytic activity of metallic surfaces toward water splitting // Journal of Catalysis. — 2010. V. 276. — № 1. -P. 92-100.

101. Song H., Mirkelamoglu B., Ozkan U.S. Effect of cobalt precursor on the performance of ceria-supported cobalt catalysts for ethanol steam reforming // Applied Catalysis A: General. 2010. - V. 382. -№1.- P. 58-64.

102. Akdim O., Demirci U.B., Muller D., Miele P. Cobalt (II) salts, performing materials for generating hydrogen from sodium borohydride // International Journal of Hydrogen Energy. 2009. - V. 34. - - № 6. - P. 2631-2637.

103. Akdim O., Demirci U.B., Miele P. More reactive cobalt chloride in the hydrolysis of sodium borohydride // International Journal of Hydrogen Energy. 2009. - V. 34. - № 23. - P. 9444-9449.

104. Liu B.H., Li Q. A highly active Co-B catalyst for hydrogen generation from sodium borohydride hydrolysis // International Journal of Hydrogen Energy. 2008. - V. 33. - № 24. - P. 7385-7391.

105. Demirci U.B., Miele P. Cobalt in NaBH» hydrolysis // Physical Chemistry Chemical Physics. -2010.-V. 12.-№44.-P. 14651-14665.

106. Akdim O., Demirci U.B., Brioude A., Miele P. Fluorinated cobalt for catalyzing hydrogen generation from sodium borohydride // International Journal of Hydrogen Energy. 2009. - V. 34. -№ 13.-P. 5417-5421.

107. Lee J., Kong K.Y., Jung C.R., Cho E., Yoon S.P., Han J., Lee T.-G., Nam S.W. A structured Co-B catalyst for hydrogen extraction from NaBHj solution // Catalysis Today. 2007. - V. 120. -№3-4.-P. 305-310.

108. Walter J.C., Zurawski A., Montgomery D., Thornburg M., Revankar S. Study of Metal Borides for Sodium Borohydride Hydrolysis // ECS Transactions. 2008. - V. 6. - № 17. - P. 55-63.

109. Wu C., Wu F., Bai Y., Yi B., Zhang H. Cobalt boride catalysts for hydrogen generation from alkalineNaBH4 solution // Materials Letters. -2005. -V. 59. -№ 14-15. -P. 1748-1751.

110. Li H., Li H., Zhang J., Dai W., Qiao M. Ultrasound-assisted preparation, of a highly active and selective Co-B amorphous alloy catalyst in uniform spherical nanoparticles 11 Journal of Catalysis. -2007. V. 246. - № 2. - P. 301-307.

111. Jeong S.U., Cho E.A., Nam S.W., Oh I.H., Jung U.H., Kim S.H. Effect of preparation method on Co-B catalytic activity for hydrogen generation from alkali NaBH4 solution // International Journal of Hydrogen Energy. 2007. - V. 32. - № 12. - P. 1749-1754.

112. Xu D., Dai P., Liu X., Cao C., Guo Q. Carbon-supported cobalt catalyst for hydrogen generation from alkaline sodium borohydride solution // Journal of Power Sources. 2008. — V. 182.-№2.-P. 616-620.

113. Dai H.-B., Liang Y., Wang P.; Cheng H.-M. Amorphous cobalt-boron/nickel foam as an effective catalyst for hydrogen generation from alkaline sodium borohydride solution // Journal of Power Sources.-2008.-V. 177.-№ l.-P. 17-23.

114. Liang J., Li Y., Huang Y., Yang J., Tang H., Wei Z., Shen P.K. Sodium borohydride hydrolysis on highly efficient Co-B/Pd catalysts // International Journal of Hydrogen Energy.2008. V. 33. - № 15. - P. 4048-4054.

115. Patel N., Fernandes R., Miotello A. Promoting effect of transition metal-doped Co-B alloy catalysts for hydrogen production by hydrolysis of alkaline NaBH4 solution // Journal of Catalysis. -2010.-V. 271.-№2.-P. 315-324.

116. Cho K.W., Kwon H.S. Effects of electrodeposited Co and Co-P catalysts on the hydrogen generation properties from hydrolysis of alkaline sodium borohydride solution // Catalysis Today. — 2007. V. 120. - № 3-4. - P. 298-304.

117. Fernandes R., Patel N., Miotello A. Efficient catalytic properties of Co-Ni-P-B catalyst powders for hydrogen generation by hydrolysis of alkaline solution of NaBFLt // International Journal of Hydrogen Energy. 2009. - V. 34. - № 7. - P. 2893-2900.

118. Fernandes R., Patel N., Miotello A., Filippi M. Studies on catalytic behavior of Co-Ni-B in hydrogen production by hydrolysis of NaBH} // Journal of Molecular Catalysis A: Chemical.2009. V. 298. - №> 1-2. - P. 1-6.

119. Cento C., Gislon P., Prosini P.P. Hydrogen generation by hydrolysis of NaBH4 // International Journal of Hydrogen Energy. 2009. - V. 34. - № 10. - P. 4551-4554.

120. Demirci U.B., Garin F. Pt catalysed hydrogen generation by hydrolysis of sodium tetrahydroborate // International Journal of Green Energy. 2008. - V. 5. - P. 148-156.

121. Demirci U.B., Garin F. Ru-based bimetallic alloys for hydrogen generation by hydrolysis of sodium tetrahydroborate // Journal of Alloys and Compounds. 2008. - V. 463. - № 1-2. - P. 107111.

122. Krishnan P., Hsueh K.-L., Yim S.-D. Catalysts for the hydrolysis of aqueous borohydride solutions to produce hydrogen for PEM fuel cells // Applied Catalysis B: Environmental. 2007. -V. 77. -№1-2. -P. 206-214.

123. Hu L., Ceccato R., Raj R. Ultrahigh figure-of-merit for hydrogen generation from sodium borohydride using ternary metal catalysts // Journal of Power Sources. 2011. - V. 196. - № 1. — P. 69-75.

124. Hammer B., Norskov J.K. Theoretical surface science and catalysis—calculations and concepts // Advances in Catalysis. 2000. - V. 45. - P. 71-129.

125. Fogler H.S., Elements of Chemical Reaction Engineering (4th Edition). San Francisco. New York. Toronto. Montreal. London. Munich. Paris. Madrid. Capetown. Sydney. Tokyo. Singapore. Mexico City, 2006. - 1080 p.

126. Yang C.-C., Chen M.-S., Chen Y.-W. Hydrogen generation by hydrolysis of sodium borohydride on CoB/SiC>2 catalyst // International Journal of Hydrogen Energy. 2011. - V. 36. -№2.-P. 1418-1423.

127. Tian H., Guo Q., Xu D. Hydrogen generation from catalytic hydrolysis of alkaline sodium borohydride solution using attapulgite clay-supported Co-B catalyst // Journal of Power Sources. 2010.-V. 195. --№8. -P. 2136-2142.

128. Zhao J., Ma H., Chen J. Improved hydrogen generation from alkaline NaBH4 solution using carbon-supported Co-B as catalysts // International Journal of Hydrogen Energy. 2007. - V. 32. -№ 18.-P. 4711-4716.

129. Xu D., Zhang H., Ye W. Hydrogen generation from hydrolysis of alkaline sodium borohydride solution using Pt/C catalyst // Catalysis Communications. 2007. V. 8. - - № 11. - P. 1767-1771.

130. Malvadkar N. Park S., Urquidi-MacDonald M., Wang H., Demirel M.C. Catalytic activity of cobalt deposited on nanostructured poly(p-xylylene) films // Journal of Power Sources. 2008. - V. 182. --№1.-P. 323-328.

131. Zhang X., Zhao J., Cheng F., Liang J., Tao Z., Chen J. Electroless-deposited Co-P catalysts for hydrogen generation from alkaline NaBHj solution // International Journal of Hydrogen Energy. -2010.-V. 35. -№ 15.-P. 8363-8369.

132. Смоликов М.Д., Джикия O.B., Затолокина E.B., Кирьянов Д.И., Белый А.С. Изомеризация н-гексана на бифункциональных Pt/S(VZr02 катализаторах //Нефтехимия. -2009. Т. 49. - № 6. - С. 488-495.

133. Ни J., Venkatesh K.R., Tierney J.W., Wender I. Reactions of aromatics and naphthenes with alkanes over a Pt/Zr02/S04 catalyst // Applied Catalysis A: General. 1994. - V. 114. - № 2. - P. L179-L186.

134. Xu D., Dai P., Guo Q., Yue X. Improved hydrogen generation from alkaline NaBH4 solution using cobalt catalysts supported on modified activated carbon // International Journal of Hydrogen Energy 2008. - V. 33. - № 24. - P. 7371-7377.

135. Akdim O., Demirci U.B., Miele P. Highly efficient acid-treated cobalt catalyst for hydrogen generation from NaBH4 hydrolysis // International Journal of Hydrogen Energy. 2009. - V. 34. -№ 11.-P. 4780-4787.

136. Krishnan P., Advani S.G., Prasad A.K. Thin-film CoB catalyst templates for the hydrolysis of NaBPLi solution for hydrogen generation // Applied Catalysis B: Environmental. 2009. - V. 86. -№3-4.-P. 137-144.

137. Yuan Z.-Z., Chen X.-D., Xu H., Qu X.-L., Wang B.-X. Crystallization kinetics of ultrafine C074 4B25 6 amorphous powder prepared by chemical reduction // Journal of Alloys and Compounds/ -2006.-V. 422.-№ 1-2.-P. 109-115.

138. Wu C., Zhang H., Yi B. Hydrogen generation from catalytic hydrolysis of sodium borohydride for proton exchange membrane fuel cells // Catalysis Today. 2004. - V. 93-95. - P. 477-483.

139. Bartholomew C.H. Mechanisms of catalyst deactivation // Applied Catalysis A: General. — 2001. -V. 212. -№ 1-2.-P. 17-60.

140. Kim J.-H., Kim K.-T., Kang Y.-M., Kim H.-S., Song M.-S., Lee Y.-J., Lee P.S., Lee J.-Y. Study on degradation of filamentary Ni catalyst on hydrolysis of sodium borohydride // Journal of Alloys and Compounds. 2004. - V. 379. -№ 1-2. - C. 222-227.

141. Xia Z.T., Chan S.H. Feasibility study of hydrogen generation from sodium borohydride solution for micro fuel cell applications // Journal of Power Sources. 2005. V. 152. - P. 46-49.

142. Chen C.-W., Chen C.-Y., Huang Y.-H. Method of preparing Ru-immobilized polymer-supported catalyst for hydrogen generation from NaBI-L solution // International Journal of Hydrogen Energy. 2009. - V. 34. - № 5. - P. 2164-2173.

143. Dai H.-B., Liang Y., Wang P. Effect of trapped hydrogen on the induction period of cobalt-tungsten-boron/nickel foam catalyst in catalytic hydrolysis reaction of sodium borohydride // Catalysis Today. 2011. - V. 170. -№ 1. - P. 27-32.

144. Cloutier C.R., Alfantaz A., Gyenge E. Physicochemical Properties of Alkaline Aqueous Sodium Metaborate Solutions // Journal of Fuel Cell Science and Technology. 2007. - V. 4. - № l.P. 88.

145. Shang Y., Chen R.Hydrogen Storage via the Hydrolysis of NaBH* Basic Solution: Optimization ofNaBELj Concentration // Energy Fuels. 2006. -V. 20. - № 5. - P. 2142-2148.

146. Tong Y.Y., van der Klink J.J. Hydrogen Adsorption on Platinum Particles Studied by 195Pt NMR // Journal of Physical Chemistry. 1994. - V. 98. -№ 43. - P. 11011-11014.

147. Табер A.M., Полковников Б.Д., Мальцева Н.Н., Михеева В.И., Баландин А.А. Исследование катализаторов, полученных реакцией борогидрида натрия с солями тяжелых металлов // Доклады акадении наук СССР. 1963. -Т. 152. - № 1. - С. 119-121.

148. Landolt D. Corrosion and Surface Chemistry of Metals. Lausanne: EPFL Press, 2007. - 632 P

149. Liu Y., Wang Y., Xiao L., Song D., Wang Y., Jiao L., Yuan H. Structure and electrochemical behaviors of a series of Co-B alloys // Electrochimica Acta. 2008. - V. 53. - - № 5. - P. 22652271.

150. Gallant D., Simard S. A study on the localized corrosion of cobalt in bicarbonate solutions containing halide ions // Corrosion Science. 2005. -V. 47. - № 7. - P. 1810-1838.

151. Фенелонов В.Б. Введение в физическую химию формирования супрамолекулярной структуры адсорбентов и катализаторов. Новосибирск: ИК СО РАН, 2002. - 413 с.

152. Kraus W., Nolze G. PowderCell for Windows (version 2.3). Federal Institute for Materials Research and Testing. Berlin. Germany. 1999.

153. Klementev K.V. Extraction of the fine structure from x-ray absorption spectra // Journal of Physics D Applied Physics. 2001. - V. 34. - № 2. - P. 209-217.

154. Rehr J. J., Ankudinov A. L. Solid state effects on X-ray absorption, emission and scattering processes // Radiation Physics and Chemistry. 2004. - V. 70. - № 1-3. - P. 453-463.

155. Duke B.J., Gulbert J.R., Read I.A. Preparation and purification of diborane // Journal of the Chemical Society. 1964. - P. 540-542.

156. Тарковская И.А. Окисленный уголь. Киев: Наукова думка, 1981. - 197 с.

157. Печенюк С.И. Сорбционно-гидролитическое осаждение платиновых металлов на поверхности неорганических сорбентов. JL: Наука, 1991. - 248 с.

158. Abrahams S. С., Kalnajs J. The Lattice Constants of the Alkali Borohydrides and the Low-Temperature Phase of Sodium Borohydride // Journal of Chemical Physics. 1954. - V. 22. - № 3. -P. 434-436.

159. Романенко A.B. Исследование катализаторов, полученных нанесением карбонильных кластеров родия на оксидные носители, в реакции гидрирования окиси углерода до низших спиртов: Дис. . к.х.н.: 02.00.15 / А.В. Романенко. ИК СО РАН. Новсибирск, 1983.

160. Chettibi S., Benguedouar Y., Keghouche N. The metal-support interaction in the oxide supported nickel nanoparticles synthesized by radiolysis // Physics Procedia. 2009. - V. 2. - № 3. -P. 707-712.

161. Socolova N. P. The effect of the "metal-support" interaction on the metallic nanosystems state // Colloids and Surfaces A: Physicochemical and Engineering Aspects. 2004. - V. 239. -№ 1-3.'-P. 125-127.

162. Beyer H., Emmerich J., Chatziapostolou K., Kohler K. Decomposition of nitrous oxide by rhodium catalysts: Effect of rhodium particle size and metal oxide support // Applied Catalysis A: General. 2011. - V. 391. - № 1 -2. - P. 411 -416.

163. Hwang C.-P., Yeh C.-T., Zhu Q. Rhodium-oxide species formed on progressive oxidation of rhodium clusters dispersed on alumina// Catalysis Today. 1999.-V. 51.-№ 1.-P. 93-101.

164. Ichikawa Т., Fujimoto S., Yoshida H. Electron spin echo study of Ti3+ in reduced Rh/Ti02 // Chemical Physics Letters. 1983. -V. 103. -№ 1. - P. 80-82.

165. Zhu H„ Qin Z., Shan W., Shen W„ Wang J. Pd/Ce02-Ti02 catalyst for CO oxidation at low temperature: a TPR study with H2 and CO as reducing agents // Journal of Catalysis. 2004. - V. 225.-№2.-P. 267-277.

166. Ливер Э. Электронная спектроскопия неорганических соединений. В 2-х частях. Часть 2. -М.: Мир, 1987.-443 с.

167. Paulhiac J. L., Clause О. Surface coprecipitation of cobalt(II), nickel(II), or zinc(II) with aluminum(III) ions during impregnation of .gamma-alumina at neutral pH // Journal of the American Chemical Society. 1993. - V. 115. - № 24. - P. 11602-11603.

168. McClure D.S. Optical Spectra of Transition-Metal Ions in Corundum // Journal of Chemical Physics. 1962. - V. 36. - № 10. - P. 2757-2779.

169. Shifu C., Sujuan Z., Wei L., Wei Z. Preparation and activity evaluation of p-n junction photocatalyst Ni0/Ti02 // Journal of Hazardous Materials. 2008. - V. 155. - № 1-2. - P. 320-326.

170. Dai Z.-M., Burgeth G., Parrino F., Kisch H. Visible light photocatalysis by a Titania-Rhodium(III) complex // Journal of Organometallic Chemistry. 2009. - V. 694. - - № 7-8. - P. 1049-1054.

171. Choi W., Termin A., Hoffmann M.R. The Role of Metal Ion Dopants in Quantum-Sized Ti02: Correlation between Photoreactivity and Charge Carrier Recombination Dynamics // Journal of Physical Chemistry. 1994. -V. 98. -№ 51. - P. 13669-13679.

172. Suriye K., Praserthdam P., Jongsomjit B. Effect of surface sites of Ti02 support on the formation of cobalt-support compound in Co/Ti02 catalysts // Catalysis Communications. 2007. -V.8.-№ll.-P. 1772-1780.

173. Chu D., Zeng Y.-P., Jiang D., Masuda Y. Room Temperature Ferromagnetism in Transition Metal Doped Ti02 Nanowires // Science of Advanced Materials. 2009. - V. 1. - № 3. - P. 227229.

174. Weng-Sieh Z., Gronsky R., Bell A.T. Microstructural Evolution of y-Alumina-Supported Rh upon Aging in Air // Journal of Catalysis. 1997. - V. 170. - № 1. - P. 62-74.

175. Ryndin Yu.A., Stenin M.V., Boronin A.I., Bukhtiyarov Y.I., Zaikovskii V.I. Effect of Pd/C dispersion on its catalytic properties in acetylene and vinylacetylene hydrogenation // Applied Catalysis. 1989. - V. 54. - № 1. - P. 277-288.

176. Эмсли Д. Элементы. M.: Мир, 1993. - 256 с.

177. Лучинский Г.П. Химия титана. M.: Химия, 1971. - 472 с.

178. Hadjiivanov K.I., Klissurski D.G. Surface chemistry of titania (anatase) and titania-supported catalysts // Chemical Society Reviews. 1996. - V. 25. - № 1. - P. 61-69.

179. Горощенко Я.Г., Белякова Е.П., Козачек H.H., Двернякова А.А., Лыкова Е.П., Парахневич Л.А., Широкова Г.А. Техническая двуокись титана и её получение из измененного ильменита сернокислотным методом. Киев: Наукова думка, 1968. — 95 с.

180. Накамото К. ИК спектры и спектры КР неорганических и координационных соединений. М.: Мир, 1991. - 536 р.

181. Corma A. Inorganic Solid Acids and Their Use in Acid-Catalyzed Hydrocarbon Reactions // Chemical Reviews.-1995.-V. 95.-№ 3.-P. 559-614.

182. Хаджииванов К.И., Давыдов A. A. // Кинетика и катализ. 1988. - V. 29. - P. 460-465.

183. Hess A., Kemnitz E. Surface acidity and catalytic behavior of modified zirconium and titanium dioxides // Applied Catalysis A: General. 1997. - V. 149. - № 2. - P. 373-389.

184. Иванов A.B., Кустов JI.M., Васина T.B., Казанский В.Б., Зойтен П. Исследование системы Pt/S04/Zr02 методом ИК-спектроскопии диффузного рассеивания // Кинетика и катализ. 1997. - Т. 38. -№ 3. - С. 438-445.

185. Stakheev A.Yu., Kustov L.M. Effects of the support on the morphology and electronic properties of supported metal clusters: modern concepts and progress in 1990s // Appl. Catal. A: General. 1999. -V. 188. - P. 3-35.

186. Cavaliere S., Hannauer J., Demirci U.B., Akdim O., Miele P. Ex situ characterization ofN2H4-, NaBILt- and МНзВНз-reduced cobalt catalysts used in NaBFLi hydrolysis // Catalysis Today. -2011. V. 170.-№ l.-P. 3-12.

187. Ma H.-C., Xue X.-Z., Liao J.-H., Liu C.-P., Xing W. Effect of borohydride as reducing agent on the structures and electrochemical properties of Pt/C catalyst // Applied Surface Science. 2006. - V. 252. - № 24. - P. 8593-8597.

188. Adlim M., Bakar M.A., Liew K.Y., Ismail J. Synthesis of chitosan-stabilized platinum and palladium nanoparticles and their hydrogenation activity // Journal of Molecular Catalysis A: Chemical.-2004. -V. 212. -№ 1-2.-P. 141-149.

189. Жигач А.Ф., Стасиневич Д.С. Химия гидридов. Л.: Химия, 1969. - 676 с.

190. Linsmeier Ch., Taglauer Е. Strong metal-support interactions on rhodium model catalysts Applied Catalysis A: General. 2011. V. 391. - № 1-2. - P. 175-186.

191. Баличева Т.Г., Лобанева О.А. Электронные и колебательные спектры неорганических и координационных соединений. Л.: Изд-во Ленинградского университета, 1983. - 120 с.

192. Connor Р.А., Dobson K.D., . McQuillan A.J. Infrared Spectroscopy of the Ti02/Aqueous Solution Interface // Langmuir. 1999. - V. 15. - № 7. - P. 2402-2408.

193. Хаджииванов К.И., Давыдов А.А., Клисурски Д.Г. ИК-спектроскопическое изучение природы активных центров на поверхности анатаза // Кинетика и катализ. 1988. - Т. 29. -№ 1.-С. 161-167.

194. Водородная связь: В сборнике / Под ред. Соколова Н.Д. М.: Наука, 1981. 286 с.

195. Hadjiivanov K.I., Klissurski D.G., Davydov A. A. Study of phosphate-modified Ti02 (anatase) // Journal of Catalysis. -1989. V. 116. - № 2. - P. 498-505.

196. Gnutzman V., Vogel W. Structural sensitivity of the standard platinum/silica catalyst EuroPt-1 to hydrogen and oxygen exposure by in situ x-ray diffraction // Journal of Physical Chemistry. -1990.-V. 94.-№ 12.-P. 4991.

197. Joyner R.W. Extended X-ray absorption fine structure (EXAFS) studies of highly dispersed platinum catalysts // Journal of the Chemical Society, Faraday Transactions: I. 1980. - V. 76. - P. 357-361.

198. Мороз Э.М., Кривенцов В.В., Кочубей Д.И. // Журнал структурной химии. 2009. - Т. 50.-№6.-С. 1132.

199. Labich S., Taglauer E., Knozinger H. Metal-support interactions on rhodium model catalysts // Topics in Catalysis.-2001.-V.-№ 14.-P. 153-161.

200. Fu Q., Wagner T. Interaction of nanostructured metal overlayers with oxide surfaces // Surface Science Reports. 2007. V. 62. - № 11. - P. 431-498.

201. Julien C. Local structure and electrochemistry of lithium cobalt oxides and their doped compounds//Solid State Ionics.-2003.-V. 157.-№ 1-4.-P. 57-71.